ELECTROREDUCTION OF ALIPHATIC ALDEHYDES ON ALUMINUM CATHODE
DOI:
https://doi.org/10.18372/2306-1472.63.8875Keywords:
carbonyl compounds, chromatography, electroreduction, hydrocarbons, oil, oxidation, regeneration, sulfuric acid-aqueous-alcohol solutionAbstract
The article represents the results of the research on the reduction of aliphatic aldehydes on aluminum in aqueous-alcohol solutions. They show that relatively high overpotential of hydrogen on aluminum cathode promotes effective processes of conversion of carbonyl compounds into the corresponding saturated and unsaturated hydrocarbons, moreover saturated products output of electrolysis increases with negative values of the operativepotential of the cathode. According to the data under controlled potential of electrolysis processes occur fast at high products output, that makes them perspective for the regeneration of used oxidized engine petroleum oils.
References
Venzel S.V. 1979. The use of lubricating oil in engines of internal burning. Moscow, “Chemistry”. 240 p. (in Russian).
Shashkin, P.I.; Bri, I.V. 1970. Regeneration of waste petroleum oils. Moscow, “Chemistry”. 303 р. (in Russian).
Gruze W.A., Stevens D.R. 1964. Technology of processing of oil: theoretical bases / Ed. Fingruta, I.Y. – Leningrad, “Chemistry”. 606 p. (in Russian).
Antropov L.I. 1993. Theoretical еlectrochemistry. Kyiv. Lybed. – 542 p. (in Ukrainian).
Ledovskykh V.M., Davydenko O.M., Rogova E.O. 2014. Cathode reduction of aliphatic aldehydes on cadmium electrode for regeneration of used motor oils. Proceedings of the National Aviation University. N 3. – С. 93-97(in English).
Tomilov A.P., Mayranovsky S.G., Fioshin M.J, Smirnov V.A. 1968. Electrochemistry of organic compounds. Leningrad, “Chemistry”. 592 p. (in Russian).
Beizer M., Lunda H. (eds.). 1988. Organic electrochemistry. Book. 1. Trans. with Eng. / Ed. V.A. Petrosyan, L.G. Feoktistov. M.: Chemistry. 496 p. (in Russian).
Lund H., Hammerich O. (eds.). 2001. Organic Electrochemistry. 4th ed., rev. and exp. Dekker. 1406 p.
