THE NEW HETEROGENEOUS CATALYTIC METHOD FOR BROMINE MALEIC ANHYDRIDE
DOI:
https://doi.org/10.18372/2310-5461.9.5033Keywords:
bromobenzene, maleic anhydride, brommaleic anhydride, oxidic vanadium-molybdenum catalyst, σ-complex, the kinetics, oxidationAbstract
The reaction of oxidation of bromobenzene on the oxide vanadium-molybdenum catalyst by oxygen was investigated, and it was found that the reaction products are maleic and brommaleic anhydrides. It was shown that di- and tribrombenzols also formed . The mechanism of their formation on the catalyst surface was considered.References
Nakajima M., Itoi K., Takamatsu Y., Sato S., Furukawa Y., Furuya K., Honma T., Kadotani J., Kozasa M., Haneishi T. // Cornexistin — a new fungal metabolite with herbicidal activity/J. Antibiot. — 1991. — V. 44. — P. 1065—1072.
Renneberg D., Pfander H., Leumann C.J. Total synthesis of coraxeniolide-A // J. Org. Chem. — 2000. — V. 65. — P. 9069—9079.
MacMillan J.H., Washburne S.S. Further Investigations of the Interaction of Trimethyl-silyl Azide with Substituted Maleic Anhydrides. Synthesis of 4- and 5-Aryl Substituted l,3-(3H)-Oxazine-2,6-diones // Journal of heterocyclic chemistry. — 1975. — V. 12. — P.1215—1219.
Патент США № 4,327,197 МКІ С07С 15. Заявл. 27.04.1982. — № 29/013,74.
Физер Л. — Органическая химия. Углубленный курс. — Т. 1 / Л. Физер, М. Физер. — М. : Химия, 1966. — 680 с.
Fischer A. 2-Bromomaleic acid //Acta Crystallographica Section E. — 2009. — V. 65. — P. 2240.
Rogstad A., Klaboe P., Cyvin B. N., Cyvin S. J., Christensen D. H. The vibrational spectra of chloro and bromo maleic anhydride // Spectrochimica Acta. Part A: Molecular Spectroscopy. — 1972. — V. 28. — P. 123—132.
Шилов E. A. Стереохимия и механизм присоединения брома по тройной связи / E. A. Шилов, И. В. Смирнов-Замков // Изв. АН СССР, ОХН. — 195I. — № I. — С. 32—41.
Augustijn G. J. P., Kooyman E. C. and Louw R.,Equilibration of benzene derivatives. Part III: Mono-and poly-substituted iodo- and bromo-benzenes // Recueil des Travaux Chimiques des Pays-Bas. —1963. —V. 82. — P. 965—975.
Патент США №4814525 МКІ С07С 15; С07С 17/152. Заявл. 25.05.1987. — № 29951.