The calorimetric inestigation of fusions of the system Ni–O and Ni–O–M
DOI:
https://doi.org/10.18372/2306-1472.45.1895Keywords:
calorimetric method, partial and integral enthalpy of mixing, desoxydating ability, law of Hess, nickel-oxygen fusionsAbstract
The enthalpy of mixing of fusions of the system Ni - O - M (M - IVb -, Vb, - VIb are metals) is studied by the calorimetric method at Т = 1780 K. Shown that the partial enthalpy of mixing for all studied systems are minus quantity. D`Ні of these fusions is confirmed by data got by E.M.F. method with a hard oxide electrolyte.
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