THERMAL INFLUENCE OF MICRODISCHARGE PLASMA ON THE PROCESS OF RECEIVING OF QUARTZ SAND ENCAPSULATED BY PYROCARBON
DOI:
https://doi.org/10.18372/2306-1472.59.6876Keywords:
high-purity silicon, microdischarge plasma, pyrocarbon, pyrolysisAbstract
The Gas Institute of National Academy of Science of Ukraine developed the facility for pyrocarbon application on the particles of quartz sand through methane pyrolysis in reactor with electrothermal fluidized bed. Thickness of the bed of pure pyrolytic carbon can be controlled within set limits, depending on the temperature, fluid dynamics and duration of the process. The formation of different types of microdischarge plasma takes place at different temperatures. Microdischarge plasma increases the temperature of the individual particles for a very short time, influencing the chemical reaction and the phase transitions passing. Quartz sand encapsulated by pyrocarbon is then used for the carbothermic reduction in order to obtain high-purity silicon.References
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Sukachev, A.I.; Kozhan, A.P.; Bogomolov, V.A. Effect by electric field on processes of pyrolysis and conversion of natural gas in fluidized bed. Chemical Industry. 1975. N 4. P. 35–37 (in Russian).
(in Russian).
Bogomolov, V.A.; Bondarenko, B.I.; Kozhan, O.P.; Simeyko, K.V. Patent of Ukraine for useful model N 83147. Reactor for pyrolysis of gaseous hydrocarbons. Date of publication 08.27.2013 (in Ukrainian).
Bogomolov, V.O.; Kozhan O.P.; Bondarenko B.I.; Hovavko O.I.; Simeyko K.V. Research of the process of encapsulation of quartz sand with pyrolytic carbon. Energy technologies and resource. P. 36–40 (in Russian).
Borodulya, V.A. High-temperature processes in electrothermal fluidized bed. Minsk, Science and Technology. 1973. 176 p. (in Russian).
Borodulya, V.A.; Vinogradov, L.M.; Grebenkov, A.J,; Rabinovich, O.S. Research of silicon carbide in the electrothermal fluidized bed. Abstracts XIX Mendeleev Congress on General and Applied Chemistry. Vol. 2. Chemistry and technology of materials, including nanomaterials. Volgograd, 2011. 26 p. (in Russian).
Borodulya, V.A.,; Vinogradov, L.M.; Grebenkov, A.G.; Mikhailov, A.A.; Sydorovych, A.M. Research of silicon carbide recovery silica petcoke in electrothermal fluidized bed. Heat-mass transfer. 2011. Sat scientific papers. Minsk: IHME them. Belarus, A.V. Lykov. 2011. P. 74–80 (in Russian).
Borodulya, V.A.; Vinogradov, L.M.; Grebenkov, A.G.; Mikhailov, A.A.; Rabinovich, O.S. Synthesis of fine silicon carbide by carbothermal reduction of silica in the electrothermal fluidized bed. IX International Conference “Silicon-2012”. Book of abstracts. Saint-Petersburg. 2012. 280 p. (in Russian).
Eremin, E.N. Fundamentals of chemical kinetics. Moscow. Higher School. 1976. 315 p.(in Russian).
Nemtchinova, N.V.; Krasin, B.A.; Kloytz, V.E. High purity metallurgical silicon a base element for solar energy. Climate and Environment: Proceedings of the Conference (21-23 April 2006. Amsterdam Holland). European journal of Natural History. 2006. N 3. P. 95–96.
Servyukov, V.N.; Martyushyn, I.G. Total electrical resistance by fluidized bed of granular material. Chemical Industry. 1967. N 6. 45–51 p. (in Russian).
Simeyko, K.V. Microplasma technology for producing of encapsulated pyrolytic carbon quartz sand by pyrolysis of methane. Energy and HEC. N 10. 2013. Minsk. 14–15 p. (in Russian).
Sorvik, Arvid. Method for the manufacture of pure Silicon Metal and amorphous silica by reduction of quartz (SiO2). Patent WO/2007/102745. Publication date: 13.09.2007.
Sukachev, A.I.; Kozhan, A.P.; Bogomolov, V.A. Effect by electric field on processes of pyrolysis and conversion of natural gas in fluidized bed. Chemical Industry. 1975. N 4. P. 35–37 (in Russian).
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Published
08-07-2014
How to Cite
Simeyko, K. (2014). THERMAL INFLUENCE OF MICRODISCHARGE PLASMA ON THE PROCESS OF RECEIVING OF QUARTZ SAND ENCAPSULATED BY PYROCARBON. Proceedings of National Aviation University, 59(2), 131–135. https://doi.org/10.18372/2306-1472.59.6876
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CHEMICAL TECHNOLOGY, HIMMOTOLOGY